By MHS, MLS (ASCP) Pasty Jarreau
Medical laboratory technological know-how assessment, a final analysis strategy fifth variation. ISBN thirteen: 9780967043432 ISBN 10: 0967043433 NU: 270 PAGES Weight: 1.76 Lbs writer: Pasty Jarreau, MHS, MLS (ASCP)
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Additional resources for Clinical Laboratory Science Review: A Bottom Line Approach, 5th Edition
Clerics doubt Christ's divinity. The Observer Newspaper, J u n e 26th, 1977. Dauben, W. G. and Payot, P. H . (1956). Radiation induced oxidation of cholesterol. Journal of the American Chemical Society, 78, 5657-5660. Diels, O . and Abderhalden, E. (1904). ζμτ Kenntniss des Cholesterins. Chemische Berichte, 37, 3092-3103. 50 T h e Biology of Cholesterol and Related Steroids Diels, O . and Gadke, W. (1927). Ü b e r die Bildung von Chrysen bei der Dehydrierung des Cholesterins. Chemische Berichte, 60, 140-147.
In 48 The Biology of Cholesterol and Related Steroids the latter case, conjugated double bonds can be formed by removal of water from the ring system. -ol and cholest-5-ene3/J,6/}-diol. Cholesterol and 7-ketocholesterol are Lifschütz-negative. Note the use of the term 'Lifschutz reaction' in two different senses is apt to be confusing. If the oxidation step with benzoyl peroxide is included, a positive colour reaction is given by many steroids with one or more double bonds in the ring system which do not give a colour with the modified procedure described above.
In this chapter, only a brief outline is given, with a few illustrative examples. In order to simplify the narrative, chemical reactions from which structural features were first deduced are described in terms of present-day knowledge of steroid chemistry, a knowledge that was not, of course, available at the time. Finally, stereochemical studies, culminating in the establishment of the absolute configuration at all centres of asymmetry, are dealt with separately although some of the relative configurations at asymmetric centres in cholesterol and bile acids had been deduced correctly from chemical evidence by 1932.
Clinical Laboratory Science Review: A Bottom Line Approach, 5th Edition by MHS, MLS (ASCP) Pasty Jarreau