By Dabiri, Homayoon E.
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Extra info for Dynamics of Human Development: Achievement Crisis (Working Paper)
To see the gist of his argument let us examine his example where two labelled molecules appear on the same side of the chemical equation: k 210 + Br2 Z 2NOBr k Suppose that isotopic bromine is added to such an equilibrium. 19) may occur, the rate of disappearance of labelled bromine (Br* — Br* or Br* — Br) will not necessarily be a first order process despite the constancy of tracee. 19). 21) indicates that the kinetics will not necessarily be linear. If [NOBr*] is low enough so that the reaction of two labelled molecules of NOBr is improbable, then the differential equations will reduce to the first order.
1)-(r-1) ( -1) C(nr S = k V h-r V*r r=1 C*(r-l) V* Let m = r-1. e. 7) the principle of chemical indistinguishability of tracer and tracee. 15) This equation has been discussed by Bergner (1961) and Norwich and Hetenyi (1971). 15) if we invoke Eq. 15) as before. 15) we must return to the open system where C is held constant in time. 15) may be written more generally t The crux of the issue is that we must use either Eq. 7) or the weighted binomial expansion Eq. 9). The same assumptions are implicit in both.
Am. Inst. Mining Metall. Eng. 175, 184-194 (1948). , Chemical Reactor Theory, An Introduction, Cambridge University Press, London, 1966. , On the generality of first-order rates in isotopic tracer kinetics, J. Theoret. Biol. 34, 509-514 (1972). , p. 67, 1962. , Chemical Reaction Engineering, Wiley, New York, 1962. , 1962. H. , Basic studies on metabolic steady state. Linearity of a metabolic tracer system, Biophysik. 7, 169-180 (1971). , 1971. , Handler, P. , Principles of Biochemistry, 4th edition, Blakiston Division, McGraw-Hill, New York, 1964.
Dynamics of Human Development: Achievement Crisis (Working Paper) by Dabiri, Homayoon E.