Get Fluorine-Containing Free Radicals. Kinetics and Dynamics of PDF

By John W. Root (Eds.)

ISBN-10: 0841203997

ISBN-13: 9780841203990

ISBN-10: 0841205159

ISBN-13: 9780841205154

content material: hassle-free response kinetics of fluorine atoms, FO, and NF loose radicals / E.H. Appelman and M.A.A. Clyne --
Reactions of radioactive ¹⁸F with alkenes, alkynes, and different substrates / F.S. Rowland, Fleet Rust, and Joan P. Frank --
Radiotracer stories of thermal hydrogen abstraction reactions via atomic fluorine / Siu-Hong Mo, Edward R. provide, Frank E. Little, Ronald G. Manning, Chester A. Mathis, Gerald S. Werre, and John W. Root --
Kinetics and mechanism of the addition of fluorine-containing radicals to olefins / J.M. Tedder and J.C. Walton --
Kinetics and mechanisms of reactions of CF, CHF, and CF₂ radicals / David S.Y. Hsu, M.E. Umstead, and M.C. Lin --
Ion-molecule reactions concerning fluorine-containing natural compounds / Sharon G. Lias --
Crossed molecular beam reports of fluorine chemistry / J.M. Farrar and Y.T. Lee --
Molecular beam reviews with F ions / Walter S. Koski --
strength disposal in reactions of fluorine atoms with polyatomic hydride molecules as studied via infrared chemiluminescence / Denis Bogan and D.W. Setser --
strength strength surfaces for fluorine-hydrogen platforms / Charles F. Bender and Henry F. Schaefer, III --
Thermochemistry of fluorocarbon radicals / Alan S. Rodgers --
Chemistry of excessive strength atomic fluorine : regular kingdom kinetic thought version calculations for the ¹⁸F + H₂ response III / Edward R. furnish, Da-Fei Feng, Joel Keizer, Kathleen D. Knierim, and John W. Root --
Electron spin resonance stories of fluorine-containing radicals in unmarried natural crystals / Lowell D. Kispert --
ESR spectra and constitution of inorganic fluorine-containing loose radicals 1 / J.R. Morton and K.F. Preston.

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Additional resources for Fluorine-Containing Free Radicals. Kinetics and Dynamics of Reactions

Example text

28). Nevertheless, Foon and Kaufman (32 ) believe that Wagner s result is the preferable one at this time. Work in the area of absolute rate constant determinations f o r fluorine atoms is still generally in the preliminary stage. The nature of tracer F experiments makes direct absolute rate determinations very difficult, while facilitating relative rate measurement. Measurements with F at various temperatures will eventually be important structed a target that can be used with cyclotron-produced fast neutrons at temperatures as high as 475 Κ (33).

Phys. (1973), 58, 757. 55. D.

Pressure" for CH FCH and CD FCD in NF , CF SF , and C F . Different pressure' scales are used for each gas—chosen to give the same visual slope for CD FCD in all four gases (7, 24, 49). ; ACS Symposium Series; American Chemical Society: Washington, DC, 1978. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1978. 4 13±1. 5 27±2. 7 2 19±2 CD Isotope Effect 137 ± 8 CH^FCHs Extrapolated Half-Stabilization P r e s s u r e s (Torr) 2 Table Χ . Extrapolated P r e s s u r e s for Half-Stabilization for Fluoroethyl Radicals in N F , C F , S F and C F Bath Gases.

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Fluorine-Containing Free Radicals. Kinetics and Dynamics of Reactions by John W. Root (Eds.)


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