By Houben J., Weyl T.
Methoden der Organischen Chemie (Methods of natural Chemistry, known as Houben-Weyl) is a regular reference paintings for chemists engaged in natural synthesis. In volumes on compound sessions, together with all Supplemental volumes, preparative tools are handled comprehensively and significantly. Tables of examples examine crucial equipment and express their scope. specified experimental strategies are given for the easiest equipment. The reactivity and extra reactions of every compound type also are provided. The vast use of formulation schemes help in making the German-language volumes extra without problems comprehensible to non-German readers.
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Extra resources for Houben-Weyl Methods in Organic Chemistry: Peptides (Synthesis / Purification)
All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s). Editorial review has deemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it. 13 Draw a line-bond structure for propyne, CH3CCH. Indicate the hybridization of each carbon, and predict a value for each bond angle.
The carbon– carbon double bond is less than twice as strong as a single bond because the sideways overlap in the p part of the double bond is not as great as the head-on overlap in the s part. 3 Commonly used in biology as a tissue preservative, formaldehyde, CH2O, contains a carbon–oxygen double bond. Draw the line-bond structure of formaldehyde, and indicate the hybridization of the carbon atom. Strategy We know that hydrogen forms one covalent bond, carbon forms four, and oxygen forms two. Trial and error, combined with intuition, is needed to fit the atoms together.
Although the figure probably looks unintelligible at this point, don’t worry; before long it will make perfectly good sense. 1 is the biological conversion of a compound called 3-hydroxy-3-methylglutaryl coenzyme A (HMG-CoA) to mevalonate, a crucial step in the pathway by which our bodies synthesize cholesterol. Also shown in the figure is an X-ray crystal structure of the active site in the HMG-CoA reductase enzyme that catalyzes the reaction, along with a molecule of the drug atorvastatin (sold under the trade name Lipitor), which binds to the enzyme and stops it from functioning.
Houben-Weyl Methods in Organic Chemistry: Peptides (Synthesis / Purification) by Houben J., Weyl T.