By Bradford P. Mundy
This moment variation is the most suitable identify source within the box. It presents a convenient source for navigating the net of named reactions and reagents. Reactions and reagents are indexed alphabetically, through suitable mechanisms, experimental facts (including yields the place available), and references to the first literature. The textual content additionally contains 3 indices according to reagents and reactions, beginning fabrics, and wanted items. natural chemistry professors, graduate scholars, and undergraduates, in addition to chemists operating in commercial, govt, and different laboratories, will all locate this publication to be a useful reference.
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Extra info for Name Reactions and Reagents in Organic Synthesis
Kalman, A. E. Sopchik, Journal ofOrganic Chemistv 1985,50,1271 Examples: Ph3P,CC4 Mexo$i; Me 0 12% Ph Ph Me 0 Ph Ph D. Seebach, A. Pichota, A. K. Beck, A. B. Pinkerton, T. Litz, J. Karjalainen, V. Gramlich, Organic Letters 1999,1,55 41 Name Reaction Ph3P, CBr4 b THF 0 63% HO 0 Br Br M. Dubber, T. K. Lindhorst, OrganicLettem 2001,2,4019 PPh3 cc14 \ OH 1 D M T 0 7 prepared in situ. immediatelyc1 reacts to give 30% overall DMTO yield ODMT (ODMTr) is the 4,4'-dimethoxytrityl group, a common -OH protecting group for the carbohydrate moieties in syntheses of' polynucleotides.
S. Struve, Organic Reactions 1,2 The Kowalski Ester Homologation provides a similar conversion (C. Kowalski, M. S. Haque, Journal of Organic Chemistry 1985, 5140) a, "yo"' + LiCHBRz 0 - OEt R-tCHZBr Li R Li R O , BuLi R Li-0 HB'BuLi_ Br EtOH )=C: Li-0-R EtO Li-0 Br Lip0 See also: P. Chen, P. T. W. Cheng, S. H. Spergel, R. Zahler, X. Wang, J. Thottathil, J. C. Barrish, R. P. Polniaszek, Tetrahedron Letters 1997,38,3 175 H - Nierenstein Reaction - 45 Name Reaction Examples: 1. O H 0 ci COOH Cl *- 2.
Deslongchamps, Journal of Organic Chemistry 2002,@, 5437 Br Me Described as a tandem Staudinger-Arbuzov Reaction: 0 0 K Me R K w N3 O E t CH2C,z P(OMe13 ~ Me R w O E t O+ ,N. Nz H Nz R = Me, Ph, 66% 78% MecOMe M. M. Sa, G. P. Sllveira, A. J. Bortoluzz~,A. Padwa, Tetrahedron 2003,59, 5441 EtO :: 4T* Na OEt 0 11 + Br/\cr;f\\ \ EtOy'OEt *'highyields" I. Pergament, M. -P. -L. Qui, M. B. Ksebati, E. A. Kern, J. Zemlicka, Tetrahedron 2002,58,6047 44 Name Reaction Arndt-Eistert Homologation Reaction The Reaction: R 1 C1 1.
Name Reactions and Reagents in Organic Synthesis by Bradford P. Mundy