The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids by Zvi Rappoport, Joel F. Liebman PDF

By Zvi Rappoport, Joel F. Liebman

ISBN-10: 047051261X

ISBN-13: 9780470512616

Concentrating on an enormous category of compounds in natural synthesis, this article beneficial properties contributions through best specialists, and supplies the standard anticipated from the “Patai Series.”

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Extra info for The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids

Example text

Oximes . . . . . . . . . . . . . . E. Hydroxamic Acids . . . . . . . . . . III. CRYSTAL PHASE STRUCTURES . . . . . . A. N−O Bond Lengths . . . . . . . . . . B. Hydroxylamine Configurations . . . . . . C. Oximes . . . . . . . . . . . . . . D. Hydroxamic Acids . . . . . . . . . . IV. SUMMARY . . . . . . . . . . . . . V. ACKNOWLEDGMENT . . . . . . . . . . VI. REFERENCES . . . . . . . . . . . . . . .

X , but also the other two, µy and µz . This is done through αxy 1. Features of hydroxylamines, oximes and hydroxamic acids 9 and αxz . Quite often, however, matters are simplified by dealing only with the average, or scalar, polarizability α (equation 9): α= 1 (αxx + αyy + αzz ) 3 (9) It has long been recognized that α correlates well with volume13, 27, 28 (equation 10): α∼V (10) ˚ . g. A polarizability should also depend inversely upon ionization enery, since I is a measure of how strongly an outer electron is held.

REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . The chemistry of hydroxylamines, oximes and hydroxamic acids Edited by Z. Rappoport and J. F. Liebman  2009 John Wiley & Sons, Ltd 29 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

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The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids by Zvi Rappoport, Joel F. Liebman


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